Ehrenfest Theorem
Also known as: Ehrenfest's Equations · Quantum-Classical Correspondence
Quantum averages obey Newton-like equations — the wavepacket's center moves classically.
A Gaussian packet sloshes in a harmonic well while a classical ball rides the same trajectory — the mean position ⟨x⟩ traces an exact classical cosine.
Equivalent forms
Newton's second law is the shadow that quantum mechanics casts on averages — exact for free particles, uniform fields, and harmonic oscillators.
Unit systems
Where it holds
Dimensional analysis
Ehrenfest, Boltzmann's student and a legendary critic at the Bohr-Einstein debates, published the two-page proof in 1927. It answered the burning question of the day: how does Newton survive inside Schrodinger's wave mechanics? Answer: as a statement about expectation values.
If everything is a wave, why does a thrown ball follow Newton's parabola?
Quantum states are fuzzy clouds, yet baseballs obey F = ma to exquisite precision. Ehrenfest's theorem shows the cloud's center of mass obeys equations that look exactly like Newton's — and tells you precisely when that resemblance becomes an identity.
- Semiclassical molecular-dynamics methods in quantum chemistry
- Designing Rydberg wavepacket experiments and their revival times
- Justifying ray optics from wave optics (the same theorem structure)
- Cold-atom accelerometers: cloud centers follow classical trajectories
- <F(x)> is NOT F(<x>) in general — the theorem does not say quantum mechanics IS classical mechanics
- The packet still spreads even while its center moves classically — Ehrenfest constrains the mean, not the width
- It does not resolve the measurement problem; it relates dynamics of averages, not outcomes of single shots
Limiting cases
What if…
The packet's wings feel different forces than its center: <x> lags the classical path, the packet disperses, then exhibits quantum revivals with no classical analog.
A dust grain's de Broglie packet is fantastically narrow, so <F(x)> (<x>) to absurd accuracy — Newtonian mechanics emerges seamlessly.
[H, gives d<E>/ — energy conservation drops out of the same theorem.
Free electron wavepacket drift
- p avg:
- 1e-24
- m:
- 9.1093837015e-31
- t:
- 1e-9
- d<x>/ <p>/
- (constant for
- delta<x>
Packet in a harmonic trap
- omega:
- 100000000000000
- x0:
- 1e-9
- -> <V'(x)> *<x> exactly
- m*d^2<x>/*<x>
- <x>: classical SHM for the mean